Chemegate

GATE 2025 Chemical Engineering, Q22 · Mass Transfer

The correct answer is B, For Penetration theory, k ∝ D_v^(1/3).

Question

If k is the mass transfer coefficient and DvD_{v} is the molecular diffusivity, which one of the following statements is NOT CORRECT with respect to mass transfer theories?

  • A. For Film theory, k Dv\propto D_{v}
  • B. For Penetration theory, k Dv1/3\propto D_{v}^{1/3}
  • C. For Surface Renewal theory, k Dv1/2\propto D_{v}^{1/2}
  • D. For Boundary Layer theory, k Dv2/3\propto D_{v}^{2/3}

Official answer: For Penetration theory, k Dv1/3\propto D_{v}^{1/3}

Why

GATE 2025 official key: (B). Higbie's penetration theory actually gives k Dv1/2,\propto D_{v}^{1/2}, not Dv1/3,D_{v}^{1/3}, making this statement the incorrect one.

Explanation cross-checked for consistency. Final answer matches the official IIT answer key.